
It is common practice in site investigations these days to monitor for soil gases. Principally these constitute methane and carbon dioxide, although other gases and vapours, such as hydrogen sulphide and solvent vapour, can be present depending on the specific site conditions.
Methane and carbon dioxide are both produced by the degradation of organic materials in made-up ground or in natural organic soils, such as peat and some types of river or marine deposits. Methane is generated, together with some carbon dioxide, when the degradation takes place in an oxygen-deficient atmosphere. In general, as the oxygen content at source increases the methane content diminishes and the carbon dioxide content increases.
Methane, carbon dioxide and other gases can also be derived from coal measures and other deep geological sources. Carbon dioxide can also be produced by some chemical reactions in the ground, particularly where carbonate rich deposits, such as lime, are present in made-up ground.
Methane is generally considered the more hazardous of the two main gases, being potentially asphyxiant but, more importantly, explosive. The gas is explosive in air at concentrations of between 5 and 15% by volume, with 5% being recognised as the lower explosive limit (LEL). The explosive limits are altered dependent on the ratio of carbon dioxide and oxygen in the atmosphere. Problems arise when there is sufficient flow from the ground to create explosive atmospheres either by gas build-up in confined spaces or by dilution from high flows and concentrations.
Thankfully, explosions due to methane from the ground are rare, with the two best known incidences being the destruction of a bungalow due to the migration of landfill gas at Loscoe, Derbyshire, in 1986. Prior to that the Abbeystead explosion of 1984, caused by an ingress of mine-gas to a water pumping station, killed 16 people who were visiting the site as part of a PR exercise.
Carbon dioxide is potentially asphyxiant and is also toxic at high concentrations. Fatalities from naturally derived carbon dioxide are extremely rare and are normally associated with volcanic events; they are, therefore, more or less non-existent in the UK. However, the gas can cause various unpleasant symptoms at low concentrations and it is implicated in sick-building syndrome. In view of these hazards, exposure to carbon dioxide is controlled by health and safety regulations in the form of short-term and long-term occupational exposure levels (1.5 and 0.5% by volume respectively).
Other hazards arise from the possible presence of other gases and organic vapours, including flammability, toxicity and odour.
Soil gas monitoring is now carried out during site investigation fieldworks to enable a full assessment of the risk from gases that might be present on a site; the presence of such gases being initially assessed from a review of the geology, history and setting of the site. This includes consideration of potential off-site sources due to the risk of migration of gas through the ground.
The extent of monitoring and the risk assessment methodology is guided by recommendations made by the Construction Industry Research and Information Association (CIRIA) and the National House Building Council (NHBC). Local Authorities will normally require monitoring in accordance with these recommendations to satisfy Planning and Building Warrant applications.
Such monitoring includes gas concentrations and flow rates, as well as groundwater levels, atmospheric pressure and atmospheric pressure trend (rising or falling). Gas sampling and analysis can be required in some cases to confirm the make up of the gas from the ground to both assist in identifying a source and to confirm that no other hazardous compounds are present.
Where soil gases are detected at hazardous concentrations and flows, mitigation measures are designed in accordance with published CIRIA or Building Research Establishment (BRE) guidance, supported by a British Standard Code of Practice (BS8485-2007). Measures can include underfloor gas barriers and/or ventilation systems, passive and active (forced) ventilations systems, and in-ground barriers and ventilation trenches to mitigate the risk of lateral gas migration (either to or from a site). The requirement for and design of such systems is entirely dependent on the individual site conditions and can only be adequately completed following the gas monitoring exercise.
A final point to ponder; it would not be the first time that we have been called in to carry out gas monitoring when an initial exercise has not been completed to an adequate standard. Cost, clearly, is an issue in these cases but often of more importance is time. Gas monitoring normally takes in the order of 2 months and, depending on site circumstances, can take up to two years to comply with the published guidance. The loss of such huge lumps of time can have a major impact on development plans. It is always best to ensure the monitoring is implemented in accordance with the relevant standards from the beginning.